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On the Solvent Dependence of Substituent Effects on Reactivities

โœ Scribed by Ritchie, C. D.; Lewis, E. S.


Book ID
120836008
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
439 KB
Volume
84
Category
Article
ISSN
0002-7863

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Solvent dielectric attenuation of substi
โœ S. Ehrenson ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 622 KB

Extension of the inhomogeneous continuum solvent model to prolate spheroidal cavity systems in the context of Kirkwood-Watheimer substituent-reactivity theory is described. Reasonable effects attributable to electrical saturation and electrostriction, which are modeled by relatively simple spatial d