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Solvent dielectric attenuation of substituent effects. Field transmission dependence on cavity boundary representation

โœ Scribed by Ehrenson, S.


Book ID
126008980
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
820 KB
Volume
104
Category
Article
ISSN
0002-7863

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Solvent dielectric attenuation of substi
โœ S. Ehrenson ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 622 KB

Extension of the inhomogeneous continuum solvent model to prolate spheroidal cavity systems in the context of Kirkwood-Watheimer substituent-reactivity theory is described. Reasonable effects attributable to electrical saturation and electrostriction, which are modeled by relatively simple spatial d