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Magnetic Field Effect in the Recombination Reaction of Radical Ion Pairs: Dependence on Solvent Dielectric Constant

✍ Scribed by Werner, U.; Staerk, H.

Book ID
121438919
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
943 KB
Volume
99
Category
Article
ISSN
0022-3654

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A pronounced solvent viscosity and polarity dependence of the magnetic field effect was found for polymethylene-linked radical ion pairs generated by photoinduced intramolecular electron transfer in compounds of the type pyrene-(CH\*),-N,N-dimethylaniline, with n = 7-16. This is interpreted in terms