Solvent effects on the magnetic field dependent recombination kinetics of the Zn-porphyrin—viologen dyad radical ion pair state
✍ Scribed by Vladimir Ya. Shafirovich; Elena E. Batova; Peter P. Levin
- Book ID
- 103667794
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 810 KB
- Volume
- 162
- Category
- Article
- ISSN
- 0301-0104
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A pronounced solvent viscosity and polarity dependence of the magnetic field effect was found for polymethylene-linked radical ion pairs generated by photoinduced intramolecular electron transfer in compounds of the type pyrene-(CH\*),-N,N-dimethylaniline, with n = 7-16. This is interpreted in terms