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Magnetic field effect on the recombination of the triple radical ion pair state of the Zn-porphyrin—violegen dyad: the influence of the supramolecule microenvironment

✍ Scribed by Vladimir Ya. Shafirovich; Elena E. Batova; Peter P. Levin

Book ID
107734935
Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
578 KB
Volume
172
Category
Article
ISSN
0009-2614

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✍ Vladimir Ya. Shafirovich; Elena E. Batova; Peter P. Levin 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 472 KB

In aqueous solutions a-and y-cyclodextrins (CDs) separate the ground state complexes of the porphyrin (P) and viologen (Vi'+) moieties in the zinc porphyrin-tetraviologen supramolecule and modulate dynamics of the connecting polymethylene chains between P and Vi\*+. Effects of the chain dynamics bei