Thermodynamic implications of substituent and solvent effects on reactivity
β Scribed by Linert, Wolfgang
- Book ID
- 118742845
- Publisher
- American Chemical Society
- Year
- 1992
- Tongue
- English
- Weight
- 711 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0095-2338
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π SIMILAR VOLUMES
Five aryl-substituted phenacetyl radicals (X = p-MeO, p-Me, H, p-Cl, p-CF 3 ) were generated by laser photolysis of the corresponding dibenzyl ketones in n-hexane and acetonitrile. The decarbonylation reaction was monitored through the rise in time-resolved absorption of the benzyl radical chromopho
The deprotonation of 4-methoxy-but-2-ynal diethyl acetal by n-butyllithium induces an acetylenicΒ±allenic isomerization (in diethylether) or a conjugated elimination reaction (in THF), providing the corresponding 1,4-dialkoxycumulene. An allenyllithium, that has been trapped as an allenylstannane, is