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On the reaction of the NH2 radical with NO at 295–620 K

✍ Scribed by V.P. Bulatov; A.A. Ioffe; V.A. Lozovsky; O.M. Sarkisov

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
460 KB
Volume
161
Category
Article
ISSN
0009-2614

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✦ Synopsis

The reaction of the NH, radical with NO, NH2 +NO+k, products, was investigated using intracavity laser spectroscopy. The temperature dependence of k, [T) over the range 295-620 K is well approximated by the expression k, ( T) = (2,0? 0.4) X 1 O-'I

x (T/298)-"' cm3 s-l. The branching ratios for the OH radical, LY= (k,,+k,,)/k,, where NHI+NO-+k,,N,H+OH+A,, N2+ H t OH, obtained at different temperatures over the range 295-620 K are as follows: a(295 K) =O. 1 kO.02; (~(470 K) =0.14 kO.03; cu(620K)=0.2+0.04.

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