Using relative rate techniques the reactions of chlorine and fluorine atoms with HC(O)F have been determined to proceed with rate constants of and respectively. Stated errors reflect statistical uncertainty; possible systematic uncertainties could add additional 10% and 20% ranges to the values of k
Cavity ring-down spectroscopic study of the kinetics of the reactions of FCO radicals with O2 and NO at 295 K
โ Scribed by Yuki Ninomiya; Masashi Goto; Satoshi Hashimoto; Masahiro Kawasaki; Timothy J. Wallington
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 127 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0538-8066
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๐ SIMILAR VOLUMES
Cavity ring-down (CRD) techniques were used to study the kinetics of the reaction of Br atoms with ozone in 1-205 Torr of either N 2 or O 2 , diluent at 298 K. By monitoring the rate of formation of BrO radicals, a value of k(Br ฯฉ O 3 ) ฯญ (1.2 ฯฎ 0.1) ฯซ 10 ฯช12 cm 3 molecule ฯช1 s ฯช1 was established th
The rate constants of the isopropyl acetate, n-propyl acetate, isopropenyl acetate, n-propenyl acetate. n-butyl acetate, and ethyl butyrate reactions with OH radicals were determined in purified air under atmospheric conditions, at 750 torr and (295 ? 2 ) K. A relative rate experimental method was u
A low-pressure discharge-flow system equipped with laser-induced fluorescence (LIF) detection of NO 2 and resonance-fluorescence detection of OH has been employed to study the self reactions CH 2 ClO 2 ฯฉ CH 2 ClO 2 : products (1) and CHCl 2 O 2 ฯฉ CHCl 2 O 2 : products (2), at T ฯญ 298 K and P ฯญ 1-3 T
The kinetics of the self-reactions of HO 2 , CF 3 CFHO 2 , and CF 3 O 2 radicals and the cross reactions of HO 2 with FO 2 , HO 2 with CF 3 CFHO 2 , and HO 2 with CF 3 O 2 radicals, were studied by pulse radiolysis combined with time resolved UV absorption spectroscopy at 295 K. The rate constants f