A low-pressure discharge-flow system equipped with laser-induced fluorescence (LIF) detection of NO 2 and resonance-fluorescence detection of OH has been employed to study the self reactions CH 2 ClO 2 ϩ CH 2 ClO 2 : products (1) and CHCl 2 O 2 ϩ CHCl 2 O 2 : products (2), at T ϭ 298 K and P ϭ 1-3 T
Kinetic studies of the self-reaction and reaction with HO2 of a tertiary β-brominated peroxy radical between 298 and 393 K
✍ Scribed by E. Villenave; R. Lesclaux
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 363 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0538-8066
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The kinetics of the self-reactions of HO 2 , CF 3 CFHO 2 , and CF 3 O 2 radicals and the cross reactions of HO 2 with FO 2 , HO 2 with CF 3 CFHO 2 , and HO 2 with CF 3 O 2 radicals, were studied by pulse radiolysis combined with time resolved UV absorption spectroscopy at 295 K. The rate constants f
Using relative rate techniques the reactions of chlorine and fluorine atoms with HC(O)F have been determined to proceed with rate constants of and respectively. Stated errors reflect statistical uncertainty; possible systematic uncertainties could add additional 10% and 20% ranges to the values of k