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Absolute rate constants for the reaction of NO3 radicals with a series of dienes at 295 K

โœ Scribed by Thomas Ellermann; Ole John Nielsen; Henrik Skov

Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
459 KB
Volume
200
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The rate constants for the reaction of NO, radicals with a series of 7 dienes, 1,3-butadiene, isoprene, 2,3dimethyl-1,3-butadiene, trans-1,3-pentadiene, cis-1,3pentadiene, trans,trans-2,4bexadiene, and LEcyclohexadiene, were measured at 295 K and at a total pressure of 1 atm. The rate constants were obtained using the absolute technique of pulse radiolysis combined with kinetic W-VIS spectroscopy. The results are discussed in terms of reactivity trends and previous literature data.

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