✦ LIBER ✦

On the reaction of protons with methane, ammonia, water and oxygen

✍ Scribed by W.T. Huntress Jr.; J.K. Kim; L.P. Theard

Publisher: Elsevier Science
Year: 1974
Tongue: English
Weight: 265 KB
Volume: 29
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(74)85009-8

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✦ Synopsis

The reactions of pro t&s with CH4, NH3, H20, Snd 02 hnve been examined by the ICR mppd ion and ion ejection methods. The reaction of HC with CH4 produces both the CHZ ion by charge transfer 2nd the CH~ ion by hydride ion abstrxtion in the ratio 2.~3, respectively. The reactions with NH3, H20, and 02 proceed cxclusiveIy by. chargs transfer. The rate constints for the reactions are: I-I+-CH4, (3.8 f 0.3).X IO-'; H+-NH3, (5.2 r. 0.5) X I@; H+-HaO, (8.2 f 0.6) X lO* ; and H+-02, (1.17 r C.09) x10+ cm3/s.

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