The reactions of pro t&s with CH4, NH3, H20, Snd 02 hnve been examined by the ICR mppd ion and ion ejection methods. The reaction of HC with CH4 produces both the CHZ ion by charge transfer 2nd the CH~ ion by hydride ion abstrxtion in the ratio 2.~3, respectively. The reactions with NH3, H20, and 02
On the mechanism of methyl ion condenstion reactions with methane, ammonia and hydrogen sulfide
β Scribed by Zeev Karpas
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 272 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The mechanism of the condensation reactions of CH 3 ions with CH4, NH 3 and H2S was studied. Apparently, neither a purely "direct" reaction nor complete equilibration of hydrogen atoms takes place. Evidence for intramolecular exchange of hydrogen atoms prior to H2 elimination was found.
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