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On the question of heavy-atom blocking of intramolecular vibrational energy transfer

โœ Scribed by S.P. Wrigley; D.A. Oswald; B.S. Rabinovitch

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
408 KB
Volume
104
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The possibility that a heavy atom can block internal ener,gy transfer in excited species has been further investigated by chemical activation study of 4Xtrimethyl lead)-2-butyl and S-(trimethyl tin)-Z-pentyi radicals. These radicals were prepared and excited by the reaction of H atoms with the corresponding I-oletins. Ener_g randomization was found to occur on a subpicosecond time scale in all the radicals studied

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