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Heavy-atom effect on the phosphorescence of charge-transfer complexes

✍ Scribed by M. Gronkiewicz; B. Kozankiewicz; J. Prochorow

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
399 KB
Volume
38
Category
Article
ISSN
0009-2614

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✦ Synopsis

I:luorcsccncc and phosphorcsccncc spectra, decay times of phosphorcsccncc and quantum-ykld ratio of phosphoruscmcc to fluorescence. for B series of charge-transfer complexes of hexamethylbenzcne (an electron donor) with phthdic anhydridc and its monohalo-and tctrahdo-dcrivativcs, have bcun measured at 90 K. It is shown that changes ofdccay times and quantum-yield ratio of phosphorcsccncc to fluorcscencc are due to the heavy-atom effect of the charge-transfer phos-pllorcscalc~.

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