Rate coefficients for the reaction of the nitrate radical with dimethyl mercury (DMHg) have been determined. The absolute rate was measured at temperatures from 258 to 358 K in the pressure range between 2.7 and 5.0 b.Pa using the fast-flow-discharge technique. The Arrhenius expression is 3.2 X 10 -
✦ LIBER ✦
On the Gas Phase Reactions Between Volatile Biogenic Mercury Species and the Nitrate Radical
✍ Scribed by Jonas Sommar; Mattias Hallquist; Evert Ljungström; Oliver Lindqvist
- Book ID
- 110230046
- Publisher
- Springer Netherlands
- Year
- 1997
- Tongue
- English
- Weight
- 155 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0167-7764
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## Abstract The bimolecular rate constant of __k__ (9.4 ± 2.4 × 10^−12^ cm^3^ molecule^−1^ s^−1^ was measured using the relative rate technique for the reaction of the nitrate radical (NO~3~•) with 4‐(2,6,6‐trimethyl‐1‐cyclohexen‐1‐yl)‐3‐buten‐2‐one (β‐ionone) at (297 ± 3) K and 1 atmosphere total