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Products and mechanism of the gas phase reaction between nitrate radical and arenes

✍ Scribed by Bruno Rindone; Franco Cariati; Gianbattista Restelli; Jens Hjorth

Book ID
112292589
Publisher
Springer
Year
1991
Tongue
English
Weight
275 KB
Volume
339
Category
Article
ISSN
1618-2650

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Rate coefficients for the reaction of the nitrate radical with dimethyl mercury (DMHg) have been determined. The absolute rate was measured at temperatures from 258 to 358 K in the pressure range between 2.7 and 5.0 b.Pa using the fast-flow-discharge technique. The Arrhenius expression is 3.2 X 10 -

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## Abstract The bimolecular rate constant of __k__ (9.4 Β± 2.4 Γ— 10^βˆ’12^ cm^3^ molecule^βˆ’1^ s^βˆ’1^ was measured using the relative rate technique for the reaction of the nitrate radical (NO~3~β€’) with 4‐(2,6,6‐trimethyl‐1‐cyclohexen‐1‐yl)‐3‐buten‐2‐one (β‐ionone) at (297 Β± 3) K and 1 atmosphere total