Comparison between the gas-phase and the solution reaction of the nitrate radical and methylarenes
β Scribed by Choidini, Germana; Rindone, Bruno; Cariati, Franco; Polesello, Stefano; Restelli, Gianbattista; Hjorth, Jens
- Book ID
- 126849840
- Publisher
- American Chemical Society
- Year
- 1993
- Tongue
- English
- Weight
- 778 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0013-936X
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π SIMILAR VOLUMES
Rate coefficients for the reaction of the nitrate radical with dimethyl mercury (DMHg) have been determined. The absolute rate was measured at temperatures from 258 to 358 K in the pressure range between 2.7 and 5.0 b.Pa using the fast-flow-discharge technique. The Arrhenius expression is 3.2 X 10 -
The kinetics of the reactions CsH,+OH( t M) +products ( + M ) ( I ) were studied at room temperature by pulse radiolysis of C2H6/H20/SFb mixtures. The ethyl radical decay was followed by monitoring the UV absorption signals at 205 nm. The experimentally determined value of k, is (7.1 f 1.0) x lOto M