The kinetics of the reactions CsH,+OH( t M) +products ( + M ) ( I ) were studied at room temperature by pulse radiolysis of C2H6/H20/SFb mixtures. The ethyl radical decay was followed by monitoring the UV absorption signals at 205 nm. The experimentally determined value of k, is (7.1 f 1.0) x lOto M
A kinetic study of the gas-phase reaction between the hydroxyl radical and atomic mercury
✍ Scribed by Jonas Sommar; Katarina Gårdfeldt; Dan Strömberg; Xinbin Feng
- Book ID
- 114377420
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 147 KB
- Volume
- 35
- Category
- Article
- ISSN
- 1352-2310
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Rate coefficients for the reaction of the nitrate radical with dimethyl mercury (DMHg) have been determined. The absolute rate was measured at temperatures from 258 to 358 K in the pressure range between 2.7 and 5.0 b.Pa using the fast-flow-discharge technique. The Arrhenius expression is 3.2 X 10 -
The kinetics of the reaction CHs + OH ( +M ) -CH,OH( + M ) was studied in the temperature range 283-373 K and in the pressure range 85-1000 mbar SF, by pulse radiolysis combined with UV absorption spectroscopy. The methyl and hydroxyl radical decays were followed by monitoring the transient UV absor