OH radical formation yields from the gas-phase reactions of O 3 with alkenes and monoterpenes
โ Scribed by Chew, Andrew A.; Atkinson, Roger
- Book ID
- 118669480
- Publisher
- American Geophysical Union
- Year
- 1996
- Tongue
- English
- Weight
- 607 KB
- Volume
- 101
- Category
- Article
- ISSN
- 0148-0227
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Using relative rate methods, rate constants have been measured for the gas-phase reactions of 3-methylfuran with NO, radicals and 0, at 296 ? 2 K and atmospheric pressure of air. The rate constants determined were (1.31 ? 0.46) X lo-'' cm' molecule-' s-' for the NO, radical reaction and (2.05 ? 0.52
Reactions of ozone with propene, 1-butene, cis-2-butene, trans-2-butene, 2,3-dimethyl-2-butene, and 1,3butadiene were carried out in Nz and air diluent at atmospheric pressure and room temperature and, by monitoring the formation of the epoxides andor a carbonyl compound formed from the reactions of