✦ LIBER ✦

Kinetics of the gas-phase reactions of NO3 radicals and O3 with 3-methylfuran and the OH radical yield from the O3 reaction

✍ Scribed by Alvaro Alvarado; Roger Atkinson; Janet Arey

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 386 KB
Volume: 28
Category: Article
ISSN: 0538-8066
DOI: 10.1002/(sici)1097-4601(1996)28:12<905::aid-kin7>3.0.co;2-r

No coin nor oath required. For personal study only.

✦ Synopsis

Using relative rate methods, rate constants have been measured for the gas-phase reactions of 3-methylfuran with NO, radicals and 0, at 296 ? 2 K and atmospheric pressure of air. The rate constants determined were (1.31 ? 0.46) X lo-'' cm' molecule-' s-' for the NO, radical reaction and (2.05 ? 0.52) X cm3 molecule-' S S ' for the 0, reaction, where the indicated errors include the estimated overall uncertainties in the rate constants for the reference reactions Based on the cyclohexanone plus cyclohexanol yield in the presence of sufficient cyclohexane to scavenge >95% of OH radicals formed, it is estimated that the 0, reaction leads to the formation of OH radicals with a yield of 0 59, uncertain to a factor of ca I 5 In the troposphere, 3-methylfuran will react dominantly with the OH radical during daylight hours, and with the NO, radical during nighttime hours for nighttime NO, radical concentrations > lo7 molecule m S 3 .

📜 SIMILAR VOLUMES

Kinetics of the gas-phase reactions of i

Kinetics of the gas-phase reactions of indan, indene, fluorene, and 9,10-dihydroanthracene with OH radicals, NO3 radicals, and O3

✍ Eric S. C. Kwok; Roger Atkinson; Janet Arey 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 191 KB 👁 2 views

The kinetics of the gas-phase reactions of OH radicals, NO 3 radicals, and O 3 with indan, indene, fluorene, and 9,10-dihydroanthracene have been studied at 297 Ϯ 2 K and atmospheric pressure of air. The rate constants, or upper limits thereof, for the O 3 reactions were (in cm 3 molecule Ϫ1 s Ϫ1 un

Erratum to “Kinetics of the gas-phase re

Erratum to “Kinetics of the gas-phase reactions of indan, indene, fluorene, and 9,10-dihydroanthracene with OH radicals, NO3 RADICALS, AND O3”

✍ >Eric S. C. Kwok; Roger Atkinson; Janet Arey 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 64 KB 👁 1 views

Gas-phase reaction of NO3 radicals with

Gas-phase reaction of NO3 radicals with isoprene: a kinetic and mechanistic study

✍ Torsten Berndt; Olaf Böge 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 233 KB 👁 1 views

The gas-phase reaction of NO 3 radicals with isoprene was investigated under flow conditions at 298 K in the pressure range 6.8 Ͻ P(mbar) Ͻ 100 using GC-MS/FID, direct MS, and long-path FT-IR spectroscopy as detection techniques. By means of a relative rate method, the rate constant for the primary

Rate constants for the gas-phase reactio

Rate constants for the gas-phase reactions of a series of C3C6 aldehydes with OH and NO3 radicals

✍ Christine Papagni; Janet Arey; Roger Atkinson 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 83 KB 👁 2 views

By using relative rate methods, rate constants for the gas-phase reactions of OH and NO 3 radicals with propanal, butanal, pentanal, and hexanal have been measured at 296 Ϯ 2 K and atmospheric pressure of air. By using methyl vinyl ketone as the reference compound, the rate constants obtained for th

Kinetics of the gas-phase reaction of CF

Kinetics of the gas-phase reaction of CF3CF2CH2OH with OH radicals and its atmospheric lifetime

✍ L. Chen; K. Fukuda; N. Takenaka; H. Bandow; Y. Maeda 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 79 KB 👁 2 views

CF 3 CF 2 CH 2 OH is a new chlorofluorocarbon (CFC) alternative. However, there are few data about its atmospheric fate. The kinetics of its atmospheric oxidation, the OH radical reaction of CF 3 CF 2 CH 2 OH, has been investigated in a 2-liter Pyrex reactor in the temperature range of 298 ϳ 356 K u

Determination of the rate constants for

Determination of the rate constants for the gas-phase reactions of methyl butenol with OH radicals, ozone, NO3 radicals, and Cl atoms

✍ Gaia Fantechi; Niels R. Jensen; Jens Hjorth; Jozef Peeters 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 141 KB 👁 2 views

Using a relative rate method, rate constants for the gas-phase reactions of 2methyl-3-buten-2-ol (MBO) with OH radicals, ozone, NO 3 radicals, and Cl atoms have been investigated using FTIR. The measured values for MBO at and total 298 Ϯ 2 K 740 Ϯ 5 torr pressure are: Ϫ11 3 Ϫ1 Ϫ1 Ϫ18 3 k ϭ (3.9 Ϯ 1.