𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Formation of OH Radicals in the Gas-Phase Reaction of Propene, Isobutene, and Isoprene with O 3 : Yields and Mechanistic Implications

✍ Scribed by Neeb, Peter; Moortgat, Geert K.

Book ID
127317805
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
128 KB
Volume
103
Category
Article
ISSN
1089-5639

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Gas-phase reaction of NO3 radicals with
Gas-phase reaction of NO3 radicals with isoprene: a kinetic and mechanistic study
✍ Torsten Berndt; Olaf BΓΆge πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 233 KB πŸ‘ 2 views

The gas-phase reaction of NO 3 radicals with isoprene was investigated under flow conditions at 298 K in the pressure range 6.8 Ο½ P(mbar) Ο½ 100 using GC-MS/FID, direct MS, and long-path FT-IR spectroscopy as detection techniques. By means of a relative rate method, the rate constant for the primary

Formation of 3-Methylfuran from the gas-
Formation of 3-Methylfuran from the gas-phase reaction of OH radicals with isoprene and the rate constant for its reaction with the OH radical
✍ Roger Atkinson; Sara M. Aschmann; Ernesto C. Tuazon; Janet Arey; Barbara Zielins πŸ“‚ Article πŸ“… 1989 πŸ› John Wiley and Sons 🌐 English βš– 590 KB

3-Methylfuran has been identified as a product of the gas-phase reaction of the OH radical with isoprene, and under simulated atmospheric conditions a formation yield of 0.044 -t 0.006 was determined. In an analogous manner, the OH radical reaction with 1,3-butadiene formed furan with a yield of 0.0

Kinetics of the gas-phase reactions of N
Kinetics of the gas-phase reactions of NO3 radicals and O3 with 3-methylfuran and the OH radical yield from the O3 reaction
✍ Alvaro Alvarado; Roger Atkinson; Janet Arey πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 386 KB πŸ‘ 2 views

Using relative rate methods, rate constants have been measured for the gas-phase reactions of 3-methylfuran with NO, radicals and 0, at 296 ? 2 K and atmospheric pressure of air. The rate constants determined were (1.31 ? 0.46) X lo-'' cm' molecule-' s-' for the NO, radical reaction and (2.05 ? 0.52