Evidence for formation of OH radicals from the reaction of O 3 with alkenes in the gas phase
โ Scribed by Paulson, Suzanne E.; Sen, Atish D.; Liu, Ping; Fenske, Jill D.; Fox, Matthew J.
- Book ID
- 119694758
- Publisher
- American Geophysical Union
- Year
- 1997
- Tongue
- English
- Weight
- 492 KB
- Volume
- 24
- Category
- Article
- ISSN
- 1944-8007
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๐ SIMILAR VOLUMES
3-Methylfuran has been identified as a product of the gas-phase reaction of the OH radical with isoprene, and under simulated atmospheric conditions a formation yield of 0.044 -t 0.006 was determined. In an analogous manner, the OH radical reaction with 1,3-butadiene formed furan with a yield of 0.0
Using relative rate methods, rate constants have been measured for the gas-phase reactions of 3-methylfuran with NO, radicals and 0, at 296 ? 2 K and atmospheric pressure of air. The rate constants determined were (1.31 ? 0.46) X lo-'' cm' molecule-' s-' for the NO, radical reaction and (2.05 ? 0.52