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Octahedral metal carbonyls: Reactions and bonding. VI Derivatives of some octahedral metal carbonyl complexes containing bidentate ligands

✍ Scribed by R. Dobson; L.W. Houk


Book ID
114041327
Publisher
Elsevier Science
Year
1967
Tongue
English
Weight
985 KB
Volume
1
Category
Article
ISSN
0020-1693

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πŸ“œ SIMILAR VOLUMES


Octahedral metal carbonyls. XLV. Kinetic
✍ Gerard R. Dobson; Ahmad Moradi-Araghi πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 English βš– 638 KB

The kinetics and mechanism of the reaction of (tmen)W(CO), (tmen = N,N,N',N'-tetramethylethylenediamine) and (tmpa)W(COj4 (tmpa = N,N,N', N'-tetramethyl-1,3diaminopropane) with phosphines and phosphites (L) to afford L,W(CO), products have been investigated in detail. For both substrates, rate data

Octahedral metal carbonyls. : XXXVII. th
✍ J.E. Pardue; G.R. Dobson πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 503 KB

Studies of the rates of reaction of the Group VI-B metal hexacarbonyls (M = 0, MO, W) with benzylamine, cyclohexylamine and aniline (amine) support a rate law, -d[M(COj6f/dt = kIIM(CO)ej + k2/M(C0)e]famineJ. The rate law is suggestive of two competing mechanisms, with the amine-independent path invo