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Octahedral metal carbonyls — XXVII Oxidative elimination reactions of Group VI-B metal carbonyl derivatives with cyanogen halides

✍ Scribed by Melvin N. Memering; Gerard R. Dobson

Book ID
118909982
Publisher
Elsevier Science
Year
1973
Weight
229 KB
Volume
35
Category
Article
ISSN
0022-1902

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Octahedral metal carbonyls. : XXXVII. th
Octahedral metal carbonyls. : XXXVII. the kinetics and mechanism of reactions of amines with the group VI-B metal carbonyls
✍ J.E. Pardue; G.R. Dobson 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 503 KB

Studies of the rates of reaction of the Group VI-B metal hexacarbonyls (M = 0, MO, W) with benzylamine, cyclohexylamine and aniline (amine) support a rate law, -d[M(COj6f/dt = kIIM(CO)ej + k2/M(C0)e]famineJ. The rate law is suggestive of two competing mechanisms, with the amine-independent path invo