✦ LIBER ✦

Octahedral metal carbonyls. XIII. Kinetics of reactions of metal carbonyl complexes containing six-membraned chelate rings

✍ Scribed by G.R. Dobson; G.C. Faber

Book ID: 114041378
Publisher: Elsevier Science
Year: 1970
Tongue: English
Weight: 608 KB
Volume: 4
Category: Article
ISSN: 0020-1693
DOI: 10.1016/s0020-1693(00)93245-6

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Octahedral metal carbonyls: Reactions an

Octahedral metal carbonyls: Reactions and bonding. VI Derivatives of some octahedral metal carbonyl complexes containing bidentate ligands

✍ R. Dobson; L.W. Houk 📂 Article 📅 1967 🏛 Elsevier Science 🌐 English ⚖ 985 KB

Octahedral metal carbonyls. 54. Rates of

Octahedral metal carbonyls. 54. Rates of chelate ring closure in five-coordinate metal carbonyl intermediates

✍ Dobson, Gerard R.; Mansour, Saber E.; Halverson, D. Eric; Erikson, Erika S. 📂 Article 📅 1983 🏛 American Chemical Society 🌐 English ⚖ 252 KB

Octahedral metal carbonyls. XLV. Kinetic

Octahedral metal carbonyls. XLV. Kinetics and mechanism of ligand exchange in tungsten carbonyl complexes containing chelating ligands bonding through nitrogen

✍ Gerard R. Dobson; Ahmad Moradi-Araghi 📂 Article 📅 1978 🏛 Elsevier Science 🌐 English ⚖ 638 KB

The kinetics and mechanism of the reaction of (tmen)W(CO), (tmen = N,N,N',N'-tetramethylethylenediamine) and (tmpa)W(COj4 (tmpa = N,N,N', N'-tetramethyl-1,3diaminopropane) with phosphines and phosphites (L) to afford L,W(CO), products have been investigated in detail. For both substrates, rate data

Mechanism of chelate ring-opening in met

Mechanism of chelate ring-opening in metal carbonyl complexes

✍ Knebel, William J.; Angelici, Robert J. 📂 Article 📅 1974 🏛 American Chemical Society 🌐 English ⚖ 701 KB

Octahedral metal carbonyls. 77. Kinetics

Octahedral metal carbonyls. 77. Kinetics of chelate ring closure via olefin-tungsten bond formation in chlorobenzene solvates of tungsten carbonyl intermediates

✍ Zhang, Shulin; Wang, I Hsiung; Wermer, Paul H.; Dobson, Charles B.; Dobson, Gera 📂 Article 📅 1992 🏛 American Chemical Society 🌐 English ⚖ 757 KB

Octahedral metal carbonyls. : XXXVII. th

Octahedral metal carbonyls. : XXXVII. the kinetics and mechanism of reactions of amines with the group VI-B metal carbonyls

✍ J.E. Pardue; G.R. Dobson 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 503 KB

Studies of the rates of reaction of the Group VI-B metal hexacarbonyls (M = 0, MO, W) with benzylamine, cyclohexylamine and aniline (amine) support a rate law, -d[M(COj6f/dt = kIIM(CO)ej + k2/M(C0)e]famineJ. The rate law is suggestive of two competing mechanisms, with the amine-independent path invo