Octahedral metal carbonyls. XLV. Kinetic
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Gerard R. Dobson; Ahmad Moradi-Araghi
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Article
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1978
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Elsevier Science
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English
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The kinetics and mechanism of the reaction of (tmen)W(CO), (tmen = N,N,N',N'-tetramethylethylenediamine) and (tmpa)W(COj4 (tmpa = N,N,N', N'-tetramethyl-1,3diaminopropane) with phosphines and phosphites (L) to afford L,W(CO), products have been investigated in detail. For both substrates, rate data