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Octahedral metal carbonyls. 77. Kinetics of chelate ring closure via olefin-tungsten bond formation in chlorobenzene solvates of tungsten carbonyl intermediates

โœ Scribed by Zhang, Shulin; Wang, I Hsiung; Wermer, Paul H.; Dobson, Charles B.; Dobson, Gerard R.


Book ID
126406059
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
757 KB
Volume
31
Category
Article
ISSN
0020-1669

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๐Ÿ“œ SIMILAR VOLUMES


Octahedral metal carbonyls. XLV. Kinetic
โœ Gerard R. Dobson; Ahmad Moradi-Araghi ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 638 KB

The kinetics and mechanism of the reaction of (tmen)W(CO), (tmen = N,N,N',N'-tetramethylethylenediamine) and (tmpa)W(COj4 (tmpa = N,N,N', N'-tetramethyl-1,3diaminopropane) with phosphines and phosphites (L) to afford L,W(CO), products have been investigated in detail. For both substrates, rate data