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Correlative studies of some spectroscopic and bonding parameters in octahedrally coordinated metal carbonyl complexes

✍ Scribed by Roland Paetzold; Sabry Abd-el-Mottaleb


Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
989 KB
Volume
24
Category
Article
ISSN
0022-2860

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## Abstract Rotation barriers around the metalβ€”pyridine bond of various macrocyclic complexes of cobalt(III), rhodium(III), zinc(II) and magnesium(II) have been studied using the ^13^C longitudinal relaxation times, __T__~1~, of the carbon atoms of pyridine and the macrocycle. The data have been ra