๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Observation of 2-azabicyclo[3.2.1]oct-1-ene, highly reactive bridgehead imine

โœ Scribed by Sheridan, Robert S.; Ganzer, George A.

Book ID
127226973
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
435 KB
Volume
105
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.

๐Ÿ“œ SIMILAR VOLUMES

New highly strained bridgehead imines, 2
New highly strained bridgehead imines, 2-azaadamant-1-ene and 4-azaprotoadamant-3-ene
โœ Tadashi Sasaki; Shoji Eguchi; Takashi Okano ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 252 KB

An azaanalog of adamantene, 2-azaadamant-1-ene (A) and 4-azaprotoadamant-3-ene ( were generated in the nonstatlstlcal ratio via photolysls of 3-azldonoradamantane ( ) The highly strained L and z could not be isolable but were trapped by MeOH Acldolysls of Z+ was

Formation and trapping of 6-azabicyclo[3
Formation and trapping of 6-azabicyclo[3.2.2]non-5-ene, a strained bridgehead imine
โœ Konrad B. Becker; Claudio A. Gabutti ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 207 KB

Photolysis or flash vacuum clo[3.2.21non-5-ene lJ, a was trapped with methanol. pyrolysis of 1-bicycloC3.2.1loctylazide 2 yields 6-azabicystrained bridgehead imine, which could not be isolated but Renewed interest in the synthesis and chemistry of bridgehead olefins (Bredt-olefins)\* has been arouse

Cation induced rearrangement of 8-azabic
Cation induced rearrangement of 8-azabicyclo[3.2.1]octa-2,6-dienes to 6-azabicyclo[3.2.1]oct-2-enes
โœ Huw M.L Davies; Guoan Cao ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 189 KB

Azabicyclic systems have been extensively used in recent years as key structural components of various pharmaceutical agents. Consequently, flexible methods for the construction of azabicycles are of considerable interest. We have recently described a very general method for the construction of trop