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New highly strained bridgehead imines, 2-azaadamant-1-ene and 4-azaprotoadamant-3-ene

✍ Scribed by Tadashi Sasaki; Shoji Eguchi; Takashi Okano

Book ID: 104219773
Publisher: Elsevier Science
Year: 1982
Tongue: French
Weight: 252 KB
Volume: 23
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)85763-9

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✦ Synopsis

An azaanalog of adamantene, 2-azaadamant-1-ene (A) and 4-azaprotoadamant-3-ene ( were generated in the nonstatlstlcal ratio via photolysls of 3-azldonoradamantane ( )

The highly strained L and z could not be isolable but were trapped by MeOH Acldolysls of Z+ was

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