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Photolysis and thermolysis of 3-azidonoradamantane. ?Anti-bredt? imines, 2-aza-adamant-1-ene, and 4-azaprotoadamant-3-ene

โœ Scribed by Jawdosiuk, Mikolaj; Kovacic, Peter


Book ID
120173107
Publisher
Royal Society of Chemistry
Year
1984
Weight
418 KB
Volume
0
Category
Article
ISSN
1472-7781

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New highly strained bridgehead imines, 2
โœ Tadashi Sasaki; Shoji Eguchi; Takashi Okano ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 252 KB

An azaanalog of adamantene, 2-azaadamant-1-ene (A) and 4-azaprotoadamant-3-ene ( were generated in the nonstatlstlcal ratio via photolysls of 3-azldonoradamantane ( ) The highly strained L and z could not be isolable but were trapped by MeOH Acldolysls of Z+ was