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Bicyclo[3.2.2]non-1-ene: matrix isolation and spectroscopic characterization of a moderately strained bridgehead olefin

โœ Scribed by Gudipati, Murthy S.; Radziszewski, Juliusz G.; Kaszynski, Piotr; Michl, Josef

Book ID
120580268
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
798 KB
Volume
58
Category
Article
ISSN
0022-3263

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Photolysis or flash vacuum clo[3.2.21non-5-ene lJ, a was trapped with methanol. pyrolysis of 1-bicycloC3.2.1loctylazide 2 yields 6-azabicystrained bridgehead imine, which could not be isolated but Renewed interest in the synthesis and chemistry of bridgehead olefins (Bredt-olefins)\* has been arouse