✦ LIBER ✦

Cation induced rearrangement of 8-azabicyclo[3.2.1]octa-2,6-dienes to 6-azabicyclo[3.2.1]oct-2-enes

✍ Scribed by Huw M.L Davies; Guoan Cao

Book ID: 104259646
Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 189 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)01221-0

No coin nor oath required. For personal study only.

✦ Synopsis

Azabicyclic systems have been extensively used in recent years as key structural components of various pharmaceutical agents. Consequently, flexible methods for the construction of azabicycles are of considerable interest. We have recently described a very general method for the construction of tropanes by a [3 + 4] annulation between rhodium-stabilized vinylcarbenoids and pyrroles/ This chemistry has been applied to the synthesis of novel dopamine and serotonin reuptake inhibitors. 2 Another bicyclic system worthy of development

📜 SIMILAR VOLUMES

ChemInform Abstract: Cation Induced Rear

ChemInform Abstract: Cation Induced Rearrangement of 8-Azabicyclo[3.2.1]octa-2,6-dienes to 6-Azabicyclo[3.2.1]oct-2-enes.

✍ H. M. L. DAVIES; G. CAO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB 👁 1 views

Unsaturated heterocyclic systems. LXXVII

Unsaturated heterocyclic systems. LXXVIII. Neighboring group participation by sulfonamide nitrogen. 7-Azabicyclo [4.2.] oct-3-ene to 6-azabicyclo[3.2.1] oct-2-ene rearrangement

✍ Paquette, Leo A.; Kelly, John F. 📂 Article 📅 1971 🏛 American Chemical Society 🌐 English ⚖ 523 KB

Epoxide Opening-Induced Tandem 8-Azabicy

Epoxide Opening-Induced Tandem 8-Azabicyclo[3.2.1]octane to 6-Azabicyclo[3.2.1]octane Rearrangement−Iminium Allylation: Synthesis of (±)-Peduncularine

✍ Hodgson, David M.; Shelton, Ruth E.; Moss, Thomas A.; Dekhane, Mouloud 📂 Article 📅 2010 🏛 American Chemical Society 🌐 English ⚖ 314 KB

ChemInform Abstract: Epoxide Opening-Ind

ChemInform Abstract: Epoxide Opening-Induced Tandem 8-Azabicyclo[3.2.1]octane to 6-Azabicyclo[3.2.1]octane Rearrangement—Iminium Allylation: Synthesis of (.+-.)-Peduncularine.

✍ David M. Hodgson; Ruth E. Shelton; Thomas A. Moss; Mouloud Dekhane 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 25 KB 👁 1 views

## Abstract The rearrangement of (I) is promoted by TmsOTf and affords (III) in high yield.

Rearrangement of nonamethylbicyclo[3.2.1

Rearrangement of nonamethylbicyclo[3.2.1]octa-3,6-dien-2-yl cation to the corresponding [3.3.0] cation

✍ Hart, Harold; Kuzuya, Masayuki 📂 Article 📅 1976 🏛 American Chemical Society 🌐 English ⚖ 655 KB

Expansive Rearrangement of N-Vinylthiazo

Expansive Rearrangement of N-Vinylthiazolidines to 2,3,4,7-Tetrahydro-1,4-thiazepines and Their Transformation in 3-Thia-6-azabicyclo[3.2.1]oct-6-enes.

✍ Luis Calvo; Alfonso Gonzalez-Ortega; Monica Perez; Maria Carmen Sanudo 📂 Article 📅 2005 🏛 John Wiley and Sons ⚖ 26 KB 👁 1 views

## Abstract For Abstract see ChemInform Abstract in Full Text.