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ChemInform Abstract: Epoxide Opening-Induced Tandem 8-Azabicyclo[3.2.1]octane to 6-Azabicyclo[3.2.1]octane Rearrangement—Iminium Allylation: Synthesis of (.+-.)-Peduncularine.

✍ Scribed by David M. Hodgson; Ruth E. Shelton; Thomas A. Moss; Mouloud Dekhane

No coin nor oath required. For personal study only.

✦ Synopsis

The rearrangement of (I) is promoted by TmsOTf and affords (III) in high yield.

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