Rearrangement of nonamethylbicyclo[3.2.1]octa-3,6-dien-2-yl cation to the corresponding [3.3.0] cation
โ Scribed by Hart, Harold; Kuzuya, Masayuki
- Book ID
- 127193955
- Publisher
- American Chemical Society
- Year
- 1976
- Tongue
- English
- Weight
- 655 KB
- Volume
- 98
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
Below -60' in FSOaH/SOzClF the nonamethyl bicyclo[3.2.1 loctadien-Pyl cation J, undergoes two degenerate rearrangements, circumambulation' and a 1,2-shift of the methano bridge.2 The first of these processes is much faster than the second, and is nmr-observable,' whereas the second process was detec
Azabicyclic systems have been extensively used in recent years as key structural components of various pharmaceutical agents. Consequently, flexible methods for the construction of azabicycles are of considerable interest. We have recently described a very general method for the construction of trop