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Mechanism of the rearrangement of bicyclo[3.2.1]octadien-2-yl cations to bicyclo[3.3.0]octadien-2-yl cations

✍ Scribed by Masayuki Kuzuya; Harold Hart

Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
165 KB
Volume
14
Category
Article
ISSN
0040-4039

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✦ Synopsis

Below -60' in FSOaH/SOzClF the nonamethyl bicyclo[3.2.1 loctadien-Pyl cation J, undergoes two degenerate rearrangements, circumambulation' and a 1,2-shift of the methano bridge.2 The first of these processes is much faster than the second, and is nmr-observable,' whereas the second process was detected only by labeling studies.2 When solutions of i in FSOaH/SO,ClF

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