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Silver-Promoted Reactions of Bicyclo[3.2.1]octadiene Derivatives.

✍ Scribed by Ravi S. Orugunty; Dennis L. Wright; Merle A. Battiste; Khalil A. Abboud


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
33
Category
Article
ISSN
0931-7597

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## Abstract The tricyclic lactams 4a–h, possessing a bicyclo[2.2.2]octadiene moiety, obtained by intramolecular Diels‐Alder reaction of the vinylidene malondiamides 1a–h, generally isomerize in boiling xylene to give the new lactams 7a–h, now bearing a bicyclo[3.2.1]octadiene part. The difference i