Mechanism of the rearrangement of bicycl
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Masayuki Kuzuya; Harold Hart
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Article
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1973
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Elsevier Science
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French
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Below -60' in FSOaH/SOzClF the nonamethyl bicyclo[3.2.1 loctadien-Pyl cation J, undergoes two degenerate rearrangements, circumambulation' and a 1,2-shift of the methano bridge.2 The first of these processes is much faster than the second, and is nmr-observable,' whereas the second process was detec