Nybomycin. IV. Total synthesis of deoxynybomycin
โ Scribed by Rinehart, Kenneth L.; Forbis, Richard M.
- Book ID
- 127091736
- Publisher
- American Chemical Society
- Year
- 1970
- Tongue
- English
- Weight
- 263 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
A stereospecific sequence from the octalindlone 2 leads In 21 steps to the new lnsecttcrde ajuqarin-IV. Formation of the butenohde portion is conveniently achteved from acid 21 by successive use of the reaqents trts(tr~methylsiloxy)ethylene and ketenyhdenetrtphenyl-phosphorane.
Rrefeldin A (9 is a macrocyclic fungal metabolite which exhibits both antibiotic and antiviral activity. A route for the total synthesis of this substance in racemic form has recently been established and reported from these laboratories. ' This note describes modifications in the synthetic sequenc