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Total synthesis of sporidesmolide IV

โœ Scribed by A.A. Kiryushkin; Yu.A. Ovchinnikov; M.M. Shemyakin


Publisher
Elsevier Science
Year
1965
Tongue
French
Weight
212 KB
Volume
6
Category
Article
ISSN
0040-4039

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A stereospecific sequence from the octalindlone 2 leads In 21 steps to the new lnsecttcrde ajuqarin-IV. Formation of the butenohde portion is conveniently achteved from acid 21 by successive use of the reaqents trts(tr~methylsiloxy)ethylene and ketenyhdenetrtphenyl-phosphorane.