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Stereoselective Total Synthesis of (+)-Norrisolide (IV).

✍ Scribed by Thomas P. Brady; Sun Hee Kim; Ke Wen; Emmanuel A. Theodorakis

Publisher
John Wiley and Sons
Year
2004
Weight
89 KB
Volume
35
Category
Article
ISSN
0931-7597

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## Abstract The cationic cyclization of 2‐[6‐(__m__‐methoxyphenyl)‐(__E__)‐3‐hexenyl]‐3,5‐dimethyl‐2‐cyclopentenol (**3**) was investigated. Exclusive formation of 1‐ and 3‐methoxy‐15Ξ±,17‐dimethyl‐1,3,5(10), 13(17)‐gonatetraene (**4** and **5**) was observed, indicating complete stereoselectivity i