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Stereospecific total synthesis of ajugarin-IV

✍ Scribed by Andrew S. Kende; Bruce Roth; Isao Kubo

Publisher: Elsevier Science
Year: 1982
Tongue: French
Weight: 259 KB
Volume: 23
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)86731-3

No coin nor oath required. For personal study only.

✦ Synopsis

A stereospecific sequence from the octalindlone 2 leads In 21 steps to the new lnsecttcrde ajuqarin-IV. Formation of the butenohde portion is conveniently achteved from acid 21 by successive use of the reaqents trts(tr~methylsiloxy)ethylene and ketenyhdenetrtphenyl-phosphorane.

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