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Nucleosides LVI. On the structure of the nucleoside antibiotic, gougerotin

✍ Scribed by Jack J. Fox; Yutaka Kuwada; Kyoichi A. Watanabe

Publisher: Elsevier Science
Year: 1968
Tongue: French
Weight: 231 KB
Volume: 9
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)70784-2

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✦ Synopsis

In a recent report ', the structure originally advanced for the nucleoside antibiotic, gougerotin, (I) 3 was revised to structure II on the basis of chemical and physical evidence.

The establishment of the carbohydrate moiety as a 4-aminohexose derivative and the positional assignment of the peptide to the 4'-amino group was determined by chemical studies 2 . The elucidation of the configuration at C-l' as beta and C-5' as; had already been shown by

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