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Nucleophilic alkylations of 3-nitropyridines

✍ Scribed by Andreassen, Einar J.; Bakke, Jan M.; Sletvold, Ingrid; Svensen, Harald

Book ID
120397933
Publisher
Royal Society of Chemistry
Year
2004
Tongue
English
Weight
284 KB
Volume
2
Category
Article
ISSN
1477-0520

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✍ Jarle Holt; Freddy Tjosås; Jan M. Bakke; Anne Fiksdahl 📂 Article 📅 2004 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 35 KB

## Abstract The nitro group of methyl 3‐nitropyridine‐4‐carboxylate (**1**) has successfully been replaced by nitrogen, oxygen and sulphur nucleophiles by nucleophilic aromatic substitution to give the 3‐azido, 3‐methoxy, 3‐phenoxy and 3‐thiophenoxypyridine‐4‐carboxylates (**2a — d**).