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Nucleophilic Alkylations of 3-Nitropyridines.

✍ Scribed by Einar J. Andreassen; Jan M. Bakke; Ingrid Sletvold; Harald Svensen

Book ID
101964870
Publisher
John Wiley and Sons
Year
2005
Weight
24 KB
Volume
36
Category
Article
ISSN
0931-7597

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## Abstract The nitro group of methyl 3‐nitropyridine‐4‐carboxylate (**1**) has successfully been replaced by nitrogen, oxygen and sulphur nucleophiles by nucleophilic aromatic substitution to give the 3‐azido, 3‐methoxy, 3‐phenoxy and 3‐thiophenoxypyridine‐4‐carboxylates (**2a — d**).