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Nuclear resonant scattering evidence of the phase co-existence during structural phase transformation in [Fe(H2O)6](ClO4)2

✍ Scribed by Gy. Vankó; L. Bottyán; L. Deák; Cs. Fetzer; G. Juhász; O. Leupold; B. Molnár; H.D. Rüter; E. Szilágyi; D.L. Nagy


Book ID
116598807
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
214 KB
Volume
401
Category
Article
ISSN
0925-8388

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The Miissbauer spectra of iron and cobalt fluoroborate hexahydrate show a change by a factor of two in the quadrupole interaction near 2%) K and 185 K, respectively, togtther with a sudden drop in resonance fraction. This behaviour is explained as a first order phase transition in which the axial pa