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A new type of phase transition in M(ClO4)2(H2O)6 M = Fe, Co, Ni and Mn

✍ Scribed by B.K. Chaudhuri


Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
366 KB
Volume
16
Category
Article
ISSN
0038-1098

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MΓΆssbauer study of the phase transitions
✍ L. Asch; I. DΓ©zsi; T. Lohner; B. MolnΓ‘r πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 205 KB

The Miissbauer spectra of iron and cobalt fluoroborate hexahydrate show a change by a factor of two in the quadrupole interaction near 2%) K and 185 K, respectively, togtther with a sudden drop in resonance fraction. This behaviour is explained as a first order phase transition in which the axial pa