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[(η6-B6X)2M] (X: C, N; M: Mn, Fe, Co, Ni): A New Class of Transition-Metal Sandwich-Type Complexes

✍ Scribed by Si-Dian Li; Jin-Chang Guo; Chang-Qing Miao; Guang-Ming Ren


Publisher
John Wiley and Sons
Year
2005
Weight
9 KB
Volume
36
Category
Article
ISSN
0931-7597

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The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.