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23Na nuclear magnetic resonance study of the phase transition in ammonium rochelle salt, NaNH4C4H4O6 • 4H2O

✍ Scribed by T. Takoshima; I. Tatsuzaki

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
245 KB
Volume
16
Category
Article
ISSN
0038-1098

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✍ L. Asch; I. Dézsi; T. Lohner; B. Molnár 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 205 KB

The Miissbauer spectra of iron and cobalt fluoroborate hexahydrate show a change by a factor of two in the quadrupole interaction near 2%) K and 185 K, respectively, togtther with a sudden drop in resonance fraction. This behaviour is explained as a first order phase transition in which the axial pa