✍ Scribed by Vladimir P. Zlomanov
No coin nor oath required. For personal study only.
The deviation from stoichiometry or nonstoichiometry characterises a homogeneity range of chemical compounds. It is determined as the difference in the nonmetal-to metal atoms ratio between a real A n B mþd (d > o0) and stoichiometric A n B m composition. Nonstoichiometry creates defects which have an effect on all properties of a crystal. The classification of defect is given. The enthalpies and entropies of quasi-chemical reactions describing the defects composition of III-V compounds are presented and give the possibility to estimate the concentration of the major defects for the solubility limits of III-V compounds.
📜 SIMILAR VOLUMES
## Abstract A new class of defects characterized by inherent non‐exponential capture and emission processes was observed. A theory – based on the potential barrier model – is proposed to describe the measured DLTS and capacitance transient data. It is argued that these defects are related to disloc
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