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Non-stereoselectivity in reductive alkylation of Δ1,9-2-octalones

✍ Scribed by P.T. Lansbury; G.E. DuBois

Book ID
104245110
Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
194 KB
Volume
13
Category
Article
ISSN
0040-4039

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✦ Synopsis

Stereoselective reductive methylation of polycyclic enones of the l-alkyl-A&' -2-octalone variety has been used advantageously by Stork et al in total syn--theses of steroids' and the triterpene lupeo12. Matthews3 has also examined

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✍ D. Gravel; J. Gauthier 📂 Article 📅 1968 🏛 Elsevier Science 🌐 French ⚖ 317 KB

A recent communication by Schuster and Brizzolara (1) prompts us to report our results on the investigation of the photochemical rearrangement of 5,10-dimethyl-5-hydroxy-A lV9-2-octalone (1). In studying the photochemistry of compound 1, it was hoped that the presence of a hydroxyl group in an appro